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This review summarizes recent progress in understanding the oxygen reduction and evolution reactions at the lanthanum strontium manganite electrode of a high-temperature solid oxide cell. Information provided here is put into the perspective of the defect chemistry of lanthanum strontium manganite and its impact on the electrode reaction mechanisms itself. After summarizing recent views on the oxygen reduction reaction mechanism, the focus turns to the oxygen evolution reaction, which is significantly less treated in the literature. A combination of the information in the literature on both reactions was the basis for modified reaction mechanism of the oxygen evolution reaction to be proposed under consideration of recent experimental observations and theoretical findings.  相似文献   
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Given a graph sequence denote by T3(Gn) the number of monochromatic triangles in a uniformly random coloring of the vertices of Gn with colors. In this paper we prove a central limit theorem (CLT) for T3(Gn) with explicit error rates, using a quantitative version of the martingale CLT. We then relate this error term to the well-known fourth-moment phenomenon, which, interestingly, holds only when the number of colors satisfies . We also show that the convergence of the fourth moment is necessary to obtain a Gaussian limit for any , which, together with the above result, implies that the fourth-moment condition characterizes the limiting normal distribution of T3(Gn), whenever . Finally, to illustrate the promise of our approach, we include an alternative proof of the CLT for the number of monochromatic edges, which provides quantitative rates for the results obtained in [7].  相似文献   
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In this paper, we study the Holder regularity of weak solutions to the Dirichlet problem associated with the regional fractional Laplacian (-△)αΩ on a bounded open set Ω ■R(N ≥ 2) with C(1,1) boundary ■Ω. We prove that when f ∈ Lp(Ω), and g ∈ C(Ω), the following problem (-△)αΩu = f in Ω, u = g on ■Ω, admits a unique weak solution u ∈ W(α,2)(Ω) ∩ C(Ω),where p >N/2-2α and 1/2< α < 1. To solve this problem, we consider it into two special cases, i.e.,g ≡ 0 on ■Ω and f ≡ 0 in Ω. Finally, taking into account the preceding two cases, the general conclusion is drawn.  相似文献   
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Corrective matrix that is derived to restore consistency of discretization schemes can significantly enhance accuracy for the inside particles in the Moving Particle Semi‐implicit method. In this situation, the error due to free surface and wall boundaries becomes dominant. Based on the recent study on Neumann boundary condition (Matsunaga et al, CMAME, 2020), the corrective matrix schemes in MPS are generalized to straightforwardly and accurately impose Neumann boundary condition. However, the new schemes can still easily trigger instability at free surface because of the biased error caused by the incomplete/biased neighbor support. Therefore, the existing stable schemes based on virtual particles and conservative gradient models are applied to free surface and nearby particles to produce a stable transitional layer at free surface. The new corrective matrix schemes are only applied to the particles under the stable transitional layer for improving the wall boundary conditions. Three numerical examples of free surface flows demonstrate that the proposed method can help to reduce the pressure/velocity fluctuations and hence enhance accuracy further.  相似文献   
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This paper studies the asymptotic behavior of coexistence steady-states of the Shigesada-Kawasaki-Teramoto model as both cross-diffusion coefficients tend to infinity at the same rate. In the case when either one of two cross-diffusion coefficients tends to infinity, Lou and Ni [18] derived a couple of limiting systems, which characterize the asymptotic behavior of coexistence steady-states. Recently, a formal observation by Kan-on [10] implied the existence of a limiting system including the nonstationary problem as both cross-diffusion coefficients tend to infinity at the same rate. This paper gives a rigorous proof of his observation as far as the stationary problem. As a key ingredient of the proof, we establish a uniform L estimate for all steady-states. Thanks to this a priori estimate, we show that the asymptotic profile of coexistence steady-states can be characterized by a solution of the limiting system.  相似文献   
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